Product ID:DIBROM CONCENTRATE, PRODUCT NO:64576
MSDS Date:07/14/1993
FSC:6840
NIIN:01-270-9765
MSDS Number: BWCHQ

VALENT USA CORP

1333 N. CALIFORNIA BLVD, SUITE 600
WALNUT CREEK, CA 94596-8025
US

Emergency Phone: 800-892-0099/800-424-9300(CHEMTREC)

Info Phone: 510-256-2700

Cage: GO545

VALENT USA CORP

8025 WALNUT CREEK, CA 94596-8025 US

Telephone: 510-256-2700/800-892-0099

Cage: GO545

DIBROM CONCENTRATE

CAS: 300-76-5

RTECS: TB9450000

Fraction By Weight: 100.0%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

NALED

CAS: 300-46-5

RTECS: TB9450000

Fraction By Weight: 85.0%

INERT INGREDIENTS & IMPURITIES IN TECHNICAL GRADE MATERIALS

Fraction By Weight: 15%

RELATED COMPOUNDS

Fraction By Weight: <8.5%

PHOSPHORIC ACID, 2,2-DICHLOROETHENYL DIMETHYL ESTER

CAS: 62-73-7

RTECS: TC0350000

Fraction By Weight: 1.5%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHYL BROMIDE (SARA III)

CAS: 74-83-9

RTECS: PA4900000

Fraction By Weight: <1.9%

OSHA PEL S, C 20 PPM

ACGIH TLV: S, 5 PPM; 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON TETRACHLORIDE (SARA III)

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.5%

OSHA PEL 10 PPM; Z-2

ACGIH TLV: S, 5 PPM; A3; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

DIMETHYL BENZENE/XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <0.2%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TRIMETHYLBENZENE

CAS: 25551-13-7

RTECS: DC3220000

Fraction By Weight: <3.4%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9394

LD50 LC50 Mixture:NOT ESTABLISHED FOR THIS MATL, SEE SUPPL
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HEALTH EFFECTS CONSISTENT
W/ORGANOPHOSPHATE POISONING.ABSORBED THRU EYE/SKIN.EYE:SEV
IRRIT,PERM EYE DAMAGE,BLINDNESS.SKIN:CORR TO SKIN & MUC
MEMB.PROLONG CONTACT INJURY,DEATH TO UNDERLYING TISSU
E.INGEST:TOXIC.CORR TO MUC MEM.INHAL:CORR TO MUC MEM.HIGHLY
TOXIC.CHRONIC:DECREASE IN CHOLINESTERASE ACTIVITY.
Explanation of Carcinogenicity:PER MSDS:CONTAIN SMAL AMTS OF CHEM
CONSIDERED TO BE PROBABLE HUMAN CANCI BY EPA BUT ANIMAL STUDIES
DON'T INDICATE.
Effects of Overexposure:EYE:PAIN,TEARS,SWELLING,REDNESS,BLURRED
VISION.HEAD,DIZZ,WEKNESS,CONSTRICTION OF PUPIL,BLURRED/DARK
VISION,EXCESSIVE SALIVATION/NASAL DISCHZRGE,PROFUSE
SWEAT,CRAMPS,NAU,DIA,VOMIT.SKIN:PAIN,FEELING OF
HEAT,DISCOLORATION,SWELLING,BLISTERING,ITCHING.INGEST:NAU,VOMIT,DIA
.INHAL:SORE THROAT,COUGH,BRONCHITIS,PULM EDEMA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFG.

First Aid:EYE:IMMED HOLD EYELIDS OPEN & FLUSH W/PLENTY OF FRESH
WATER.REMOVE CONTACT LENSES IF WORN.GET MED ATTN IMMED. SKIN:REMOVE
CONTAMIN CLOTH.WASH THOROUGHLY W/SOAP & WATER.SEE DR
IMMED.INGEST:DRINK 1 OR 2 GLASSES OF WATER OR MILK.INDUCE VOMIT BY
TOUCHING BACK OF THROAT W/FINGER.CALL DR/POI CNTRL CNTR/EMERG CNTR
BEFORE INDUCING VOMIT.TAKE TO NEAREST EMERG CTNR.INHAL:MOVE TO
FRESH AIR.(SEE SUPPLEMTN).

Flash Point:116F,47C
Lower Limits:1
Upper Limits:7
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:AVOID BREATH SMOKE/MIST & PERSONNEL/EQPMT
CONTACT W/FALLOUT/RUNOFF.MIN AMT OF WATER USED FOR
FIREFIGHTING.DON'T ENTER ENCLSD AREA W/O FULL PROT EQPMT.DECONTAMIN
Unusual Fire/Explosion Hazard:LIQ EVAPORATES,FORMS VAP WHICH CATCHES
FIRE & BURN W/EXPLO VIOLENCE.INVISIBLE VAP SPREADS EASILY.FIRE HAZ
GREATER AS LIQ TEMP RISES >85F.COMBUST PROD TOXIC.

Spill Release Procedures:FOR HELP W/ANY SPILL/LEAK/FIRE/EXPO OF MATL
CALL DAY/NIGHT 800-892-0099.REMOVE IGN SOURCES.CLEANUP IMMED.COVER
SPILL W/GENEROUS AMT OF OIL DRY/CATLITTER/CLAY/RAGS/OTHER
ABSORBENT.MIX WELL W/STIFF BRRO M.SWEEPUP INTO DISPO CNTNR.SCRUB
ARE W/DETER/WATER
Neutralizing Agent:NONE SPECIFIED BY MFG.

Handling and Storage Precautions:KEEP IN ORIGINAL CNTNR.DO NOT
STORE/TRANSP NEAR FOOD/FEED.DO NOT CONTAMIN FOOD/FEED,PUT CONCEN
INTO FOOD/DRINK CNTNRS.DO NOT DILUTE IN FOOD/DRINK CNTR
Other Precautions:DON'T USE/STORE NEAR FLAME/SPARKS/HOT SURFACES.USE
ONLY IN WELL VENTI AREA.KEEP CNTNR CLSD.DON'T WELD/HEAT/DRILL
CNTNR.REPLACE CAP/BUNG.EMPTIED CNTNR STILL CONTAINS HAZ/EXPLO
VAP/LIQ.DON'T APPLY DIREC TLY TO WATER EXCEPT WHEN USED OVER WATER

Respiratory Protection:WEAR APPROVED RESPIRATORY PROTECTION WHEN
WORKING W/THIS MATERIAL.AN AIR-SUPPLING RESP IS RECOMMENDED.
Ventilation:MUST BE DEMONSTRATED TO BE ADEQUATE TO KEEP AIRBORNE CONCEN
OF MATRL BELOW RECOMMENDED EXPOUSRE STDS PRIOR TO USING MATL
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL GOGGLES OR FACESHIELD.
Other Protective Equipment:IMPERVIOUS PROTECTIVE
CLOTHING,APRON,OVERSHOES,COMPLETE FACIAL PROTECTION.
Work Hygienic Practices:WASH HANDS AFTER HANDLING.DISCARD CONTAM
NONWATERPROOF SHOES/BOOTS.WASH CONTAM CLOTHING PRIOR TO REUSE.
Supplemental Safety and Health
LD50,ORAL,RAT FOR SIMILAR PRODUCT (NALED TECHNICAL)=191MG/KG MALE,
92MG/KG FEMALE. 1STAID:GIVE ART RESP IF NOT
BREATH.PHYSICIAN:CONTAINS CHOLINESTERASE INHIBITOR.IF SIGNS OF
INHIBITION APPEARS ATROPIN E SULFATE IS ANTIDOTAL.2-PAM(PROTOPAM)
IS ANTIDOTAL & MAY BE USED IN CONJUCTION W/ATROPINE BUT SHOULD NOT
BE USED ALONE.

HCC:F4
Boiling Pt:B.P. Text:320F,160C
Vapor Pres:10MM @100F
Solubility in Water:SLIGHTLY SOLUBLE.
Appearance and Odor:LIGHT STRAW-COLORED LIQUID WITH SLIGHTLY PUNGENT
ODOR.

Stability Indicator/Materials to Avoid:YES
IRON OR ALKALINE MEDIA. CORROSIVE TO ALUMINUM & MAGNESIUM. HYDROLYZES
SLOWLY UNDER NEUTRAL OR ACID CONDITIONS.
Stability Condition to Avoid:MAY BE PHOTOCHEMICALLY REACTIVE.
Hazardous Decomposition Products:CARBON DIOXIDE,WATER VAP,OXIDES OF
PHOSPHORUS.TOXIC COMPDS OF CHLORINE & BROMINE.CARBON MONOXIDE FROM
INCOMPLETE COMBUST

Waste Disposal Methods:NONE SPECIFIED BY MFG. HOWEVER DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.TOXIC TO
WILDLIFE & AQUATIC ORGANISMS,HIGHLY TOXIC TO BEES EXPO TO DIRECT
TRETMENT/RESIDUE ON BLOOMING CROPS/WEEDS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.